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Denture Resin Material Safety Data Sheet (MSDS)

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Denture Resin Material Safety Data Sheet

SECTION I: Identification of the substance / mixture and of the company / undertaking

1.1. Product identifier
Product name Powerresins Denture Resin

1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses 
Light curing resin for removable base plates manufacturing.

Uses advised against 
No specific uses advised against are identified.
1.3. Details of the supplier of the safety data sheet 

Supplier 

3BFAB TEKNOLOJİ A.Ş. 
Ihlamurkuyu Mah.
Çanakkale Cad. Eren Plaza No: 5 Kat: 4 PK: 34771
Ümraniye / İstanbul / TURKEY Tel: +90 216 612 00 94 www.3bfab.com

 1.4. Emergency telephone number 

Emergency telephone 3BFAB: +90 216 612 00 94

 
 

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical hazards                                  Not Classified
Health hazards.                                    Skin Sens. 1 - H317 Repr. 2 - H361f
Environmental hazards                       Aquatic Chronic 3 - H412


2.2. Label elements
Hazard pictograms 

Signal word
Warning

Hazard statements
H317 May cause an allergic skin reaction.
H361f Suspected of damaging fertility.
H412 Harmful to aquatic life with long lasting effects.


Precautionary statements
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection / face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P501 Dispose of contents/ container in accordance with national regulations.

Contains 
7,7,9(or 7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12-diazahexadecane-1,16-diyl bismethacrylate, diphenyl(2,4,6- trimethylbenzoyl)phosphine oxide

2.3. Other hazards
This product does not contain any substances classified as PBT or vPvB.

 
 

SECTION 3: Composition / Information on Ingredient

3.2. Mixtures

Esterification products of 4,4'-isopropylidenediphenol, ethoxylated
and 2-methylprop-2-enoic acid
CAS number: 41637-38-1
40-60%
Classification
Aquatic Chronic 4 - H413
7,7,9(or 7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12-
diazahexadecane-1,16-diyl bismethacrylate
CAS number: 72869-86-4
10-20%
Classification
Skin Sens. 1B - H317
Aquatic Chronic 2 - H411
Titanium dioxide 
CAS number: 13463-67-7                           EC number: 236-675-5
5-10%
Classification
Not Classified
diphenyl(2,4,6- trimethylbenzoyl)phosphine oxide
CAS number: 75980-60-8                         EC number: 278-355-8
1-5%
Classification
Skin Sens. 1 - H317
Repr. 2 - H361f
Aquatic Chronic 2 - H411

The full text for all hazard statements is displayed in Section 16.

 
 

SECTION 4: First aid measures

4.1. Description of first aid measures


General information 
Get medical attention immediately. Show this Safety Data Sheet to the medical personnel.


Inhalation 
Remove affected person from source of contamination. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Maintain an open airway. Loosen tight clothing such as collar, tie or belt. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Place unconscious person on their side in the recovery position and ensure breathing can take place.

Ingestion 
Rinse mouth thoroughly with water. Remove any dentures. Give a few small glasses of water or milk to
drink. Stop if the affected person feels sick as vomiting may be dangerous. Do not induce vomiting unless under the direction of medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Place unconscious person on their side in the recovery position and ensure breathing can take place. Maintain an open airway. Loosen tight clothing such as collar, tie or belt.

Skin contact 

It is important to remove the substance from the skin immediately. In the event of any sensitisation
symptoms developing, ensure further exposure is avoided. Remove contamination with soap and water or recognised skin cleansing agent. Get medical attention if symptoms are severe or persist after washing.

Eye contact 
Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 10 minutes.

Protection of first aiders
First aid personnel should wear appropriate protective equipment during any rescue. Wash contaminated clothing thoroughly with water before removing it from the affected person, or wear gloves.

4.2. Most important symptoms and effects, both acute and delayed


General information
See Section 11 for additional information on health hazards. The severity of the symptoms described will vary dependent on the concentration and the length of exposure.


Inhalation 
Prolonged inhalation of high concentrations may damage respiratory system.
 

Ingestion 
May cause sensitisation or allergic reactions in sensitive individuals. Gastrointestinal symptoms, including upset stomach. Fumes from the stomach contents may be inhaled, resulting in the same symptoms as inhalation.

Skin contact 

May cause skin sensitisation or allergic reactions in sensitive individuals. Prolonged contact may cause
dryness of the skin.

Eye contact 
May cause temporary eye irritation.


4.3. Indication of any immediate medical attention and special treatment needed


Notes for the doctor 
Treat symptomatically. May cause sensitisation or allergic reactions in sensitive individuals.

 
 

SECTION 5: Fire-Fighting Measures

5.1. Extinguishing media

Suitable extinguishing media 
The product is not flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Use fire-extinguishing media suitable for the surrounding fire.

Unsuitable extinguishing media 
Do not use water jet as an extinguisher, as this will spread the fire.


5.2. Special hazards arising from the substance or mixture

Specific hazards 
Containers can burst violently or explode when heated, due to excessive pressure build-up.

Hazardous combustion products
Thermal decomposition or combustion products may include the following substances: Harmful gases or vapours.

 

5.3. Advice for firefighters


Protective actions during firefighting
Avoid breathing fire gases or vapours. Evacuate area. Keep upwind to avoid inhalation of gases, vapours, fumes and smoke. Ventilate closed spaces before entering them. Cool containers exposed to heat with water spray and remove them from the fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. If a leak or spill has not ignited, use water spray to disperse vapours and protect men stopping the leak. Avoid discharge to the aquatic environment. Control run-off water by containing and keeping it out of sewers and watercourses. If risk of water pollution occurs, notify appropriate authorities.

Special protective equipment for firefighters
Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing.
Firefighter's clothing conforming to European standard EN469 (including helmets, protective boots and
gloves) will provide a basic level of protection for chemical incidents.

 
 

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions 
No action shall be taken without appropriate training or involving any personal risk. Keep unnecessary and unprotected personnel away from the spillage. Wear protective clothing as described in Section 8 of this safety data sheet. Follow precautions for safe handling described in this safety data sheet. Wash thoroughly after dealing with a spillage. Ensure procedures and training for emergency decontamination and disposal are in place. Do not touch or walk into spilled material. Avoid contact with skin and eyes.

6.2. Environmental precautions
Environmental precautions
Avoid discharge into drains or watercourses or onto the ground. Avoid discharge to the aquatic environment. Large Spillages: Inform the relevant authorities if environmental pollution occurs (sewers, waterways, soil or air).

6.3. Methods and material for containment and cleaning up
Methods for cleaning up 
Wear protective clothing as described in Section 8 of this safety data sheet. Approach the spillage from upwind. Small Spillages: If the product is soluble in water, dilute the spillage with water and mop it up.
Alternatively, or if it is not water-soluble, absorb the spillage with an inert, dry material and place it in a suitable waste disposal container. Large Spillages: If leakage cannot be stopped, evacuate area. Flush spilled material into an effluent treatment plant, or proceed as follows. Contain and absorb spillage with sand, earth or other non- combustible material. Place waste in labelled, sealed containers. Clean contaminated objects and areas thoroughly, observing environmental regulations. The contaminated absorbent may pose the same hazard as the spilled material. Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage. Dangerous for the environment. Do not empty into drains. Dispose of waste to
licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority.

6.4. Reference to other sections
Reference to other sections 
For personal protection, see Section 8. See Section 11 for additional information on health hazards. See
Section 12 for additional information on ecological hazards. For waste disposal, see Section 13.

 
 

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions
Read and follow manufacturer's recommendations. Wear protective clothing as described in Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs. Handle all packages and containers carefully to minimise spills. Keep container tightly sealed when not in use. Avoid the formation of mists. Suspected of damaging fertility. Avoid discharge to the aquatic environment. Do not handle until all safety precautions have been read and understood. Do not handle broken packages without protective equipment. Do not reuse empty containers.

Advice on general occupational hygiene 
Wash promptly if skin becomes contaminated. Take off contaminated clothing. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Wash at the end of each work shift and before eating, smoking and using the toilet. Change work clothing daily before leaving workplace.

7.2. Conditions for safe storage, including any incompatibilities
Storage precautions 
Store away from incompatible materials (see Section 10). Store in accordance with local regulations. Keep only in the original container. Keep container tightly closed, in a cool, well ventilated place. Keep containers upright. Protect containers from damage. Bund storage facilities to prevent soil and water pollution in the event of spillage. The storage area floor should be leak-tight, jointless and not absorbent.

7.3. Specific end use(s)
Specific end use(s) 
The identified uses for this product are detailed in Section 1.2.

 
 

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits
Titanium dioxide
Inhalable Total dust: 15 (mg / m3) Quantity Total Dust TWA

                                         Titanium dioxide (CAS: 13463-67-7)
DNEL                                Workers - Inhalation; Long term local effects: 10 mg/m3
                                         Consumer - Oral; Long term systemic effects: 700 mg/kg/day

8.2. Exposure controls

Protective equipment

Appropriate engineering controls 
Provide adequate ventilation. Personal, workplace environment or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Use process enclosures, local exhaust ventilation or other engineering controls as the primary means to minimise worker exposure. Personal protective equipment should only be used if worker exposure cannot be controlled adequately by the engineering control measures. Ensure control measures are regularly inspected and maintained. Ensure operatives are trained to minimise exposure.

Eye/face protection 
Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. Personal protective equipment for eye and face protection should comply with European Standard EN166. Unless the assessment indicates a higher degree of protection is required, the following protection should be worn: Tight-fitting safety glasses.

Hand protection
Chemical-resistant, impervious gloves complying with an approved standard should be worn if a risk assessment indicates skin contact is possible. The most suitable glove should be chosen in consultation with the glove supplier/manufacturer, who can provide information about the breakthrough time of the glove material. To protect hands from chemicals, gloves should comply with European Standard EN374. Considering the data specified by the glove manufacturer, check during use that the gloves are retaining their protective properties and change them as soon as any deterioration is detected. Frequent changes
are recommended. For exposure up to 4 hours, wear gloves made of the following material: Butyl rubber. Nitrile rubber.

Other skin and body protection 
Appropriate footwear and additional protective clothing complying with an approved standard should be worn if a risk assessment indicates skin contamination is possible.

Hygiene measures
Provide eyewash station and safety shower. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Clean equipment and the work area every day. Good personal hygiene procedures should be implemented. Wash at the end of each work shift and before eating, smoking and using the toilet. When using do not eat, drink or smoke. Preventive industrial medical examinations should be carried out. Warn cleaning personnel of any hazardous properties of the product.

Respiratory protection 
Respiratory protection complying with an approved standard should be worn if a risk assessment indicates inhalation of contaminants is possible. Ensure all respiratory protective equipment is suitable for its intended use and is ‘CE’-marked. Check that the respirator fits tightly and the filter is changed regularly. Gas and combination filter cartridges should comply with European Standard EN14387. Full face mask respirators with replaceable filter cartridges should comply with European Standard EN136. Half mask and quarter mask respirators with replaceable filter cartridges should comply with European Standard EN140.

Environmental exposure controls
Keep container tightly sealed when not in use. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Store in a demarcated bunded area to prevent release to drains and/or watercourses.

 
 

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance                                                                Liquid.

Colour Transparent.                                                  Pink.

Odour                                                                         Odourless.

Odour threshold                                                        No information available.

pH                                                                               No information available.

Melting point                                                             No information available.

Initial boiling point and range                                 No information available.

Flash point                                                                 No information available.

Evaporation rate                                                       No information available.

Flammability (solid, gas)                                          No information available.

Upper/lower flammability or explosive limits        No information available.

Vapour pressure                                                       No information available.

Vapour density                                                         No information available.

Solubility(ies)                                                            No information available.

Auto-ignition temperature                                      Product is not selfigniting.

Decomposition Temperature                                  300°C

Viscosity                                                                   1900-2200 MPa

Explosive properties                                                No information available.

Oxidising properties                                                No information available.

9.2. Other information

Other information                                                  No information required.

 
 

SECTION 10: Stability and reactivity

10.1. Reactivity

Reactivity 
There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stability
Stable at normal ambient temperatures and when used as recommended. Stable under the prescribed storage conditions.

10.3. Possibility of hazardous reactions

Possibility of hazardous reactions 
No potentially hazardous reactions known.

10.4. Conditions to avoid

Conditions to avoid
Avoid excessive heat for prolonged periods of time. Containers can burst violently or explode when heated, due to excessive pressure
build-up.

10.5. Incompatible materials

Materials to avoid
No specific material or group of materials is likely to react with the product to produce a hazardous situation.

10.6. Hazardous decomposition products

Hazardous decomposition products
Does not decompose when used and stored as recommended. Thermal decomposition or combustion products may include the following substances: Harmful gases or vapours.

 
 

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral 
Notes (oral LD₅₀)                                       Based on available data the classification criteria are not met.

Acute toxicity - dermal 
Notes (dermal LD₅₀).                                Based on available data the classification criteria are not met.

Acute toxicity - inhalation.
Notes (inhalation LC₅₀)                            Based on available data the classification criteria are not met.

Serious eye damage/irritation
Serious eye damage/irritation               Based on available data the classification criteria are not met.

Respiratory sensitisation
Respiratory sensitisation                        Based on available data the classification criteria are not met.

Skin sensitisation
Skin sensitisation                                    May cause skin sensitisation or allergic reactions in sensitive individuals.

Germ cell mutagenicity
Genotoxicity - in vitro                             Based on available data the classification criteria are not met.

Carcinogenicity
Carcinogenicity                                       Based on available data the classification criteria are not met.

IARC carcinogenicity                               None of the ingredients are listed or exempt.

Reproductive toxicity
Reproductive toxicity - fertility               Suspected of damaging fertility.

Reproductive toxicity -
development                                            Based on available data the classification criteria are not met.

Specific target organ toxicity - single exposure
STOT - single exposure                            Not classified as a specific target organ toxicant after a single exposure.

Specific target organ toxicity - repeated exposure
STOT - repeated exposure                       Not classified as a specific target organ toxicant after a single exposure.

Aspiration hazard
Aspiration hazard                                    Based on available data the classification criteria are not met.

General information                                May damage fertility. The severity of the symptoms described will vary dependent on the concentration and the length of exposure.

Inhalation                                                  Prolonged inhalation of high concentrations may damage respiratory system.

Ingestion                                                    May cause sensitisation or allergic reactions in sensitive individuals. Gastrointestinal symptoms, including upset stomach. Fumes from the stomach contents may be inhaled, resulting in the same symptoms as inhalation.

Skin contact                                               May cause skin sensitisation or allergic reactions in sensitive individuals. Prolonged contact may cause dryness of the skin.

Eye contact                                                May cause temporary eye irritation.

Route of exposure                                    Ingestion Inhalation Skin and/or eye contact

Target organs                                           No specific target organs known.

Medical considerations                           Skin disorders and allergies.

 
 

SECTION 12: Ecological information

12.1. Toxicity

Toxicity                                                      Aquatic Chronic 3 - H412 Harmful to aquatic life with long lasting effects.

12.2. Persistence and degradability

Persistence and degradability                The degradability of the product is not known.

12.3. Bioaccumulative potential

Bioaccumulative potential                      No data available on bioaccumulation.

12.4. Mobility in soil

Mobility                                                    The product contains volatile substances which may spread in the atmosphere.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB assessment.     This product does not contain any substances classified as PBT or vPvB.

12.6. Other adverse effects

Other adverse effects                               None known.

 
 

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information 
Reuse or recycle products wherever possible. This material and its container must be disposed of in a safe way. When handling waste, the safety precautions applying to handling of the product should be considered. Care should be taken when handling emptied containers that have not been thoroughly cleaned or rinsed out. Empty containers or liners may retain some product residues and hence be potentially hazardous.

Disposal methods 
Do not empty into drains. Dispose of surplus products and those that cannot be recycled via a licensed waste disposal contractor. Waste, residues, empty containers, discarded work clothes and contaminated cleaning materials should be collected in designated containers, labelled with their contents.

 
 

SECTION 14: Transport information

General 
The product is not covered by international regulations on the transport of dangerous goods (IMDG, IATA,
ADR/RID).

14.1. UN number                                       
Not applicable.

14.2. UN proper shipping name
Not applicable.

14.3. Transport hazard class(es)
No transport warning sign required.

14.4. Packing group
Not applicable.

14.5. Environmental hazards
Environmentally hazardous substance/marine pollutant
No.

14.6. Special precautions for user
Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to
Annex II of MARPOL 73/78 and the IBC Code
Not applicable

 
 

SECTION 15: Regulatory Information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

National regulations 
Health and Safety at Work etc. Act 1974 (as amended). The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009 (SI 2009 No. 1348) (as amended) ["CDG 2009"]. EH40/2005 Workplace exposure limits.

EU legislation 
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (as amended). Commission Regulation (EU) No 2015/830 of 28 May 2015. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended).

Seveso Directive - Control of major accident hazards
Not applicable.

15.2. Chemical safety assessment
No chemical safety assessment has been carried out.

 
 

SECTION 16: Other information

Abbreviations and acronyms used in the safety data sheet
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.
ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways.
RID: European Agreement concerning the International Carriage of Dangerous Goods by Rail.
IATA: International Air Transport Association.
ICAO: Technical Instructions for the Safe Transport of Dangerous Goods by Air.
IMDG: International Maritime Dangerous Goods.
CAS: Chemical Abstracts Service.
ATE: Acute Toxicity Estimate.
LC₅₀: Lethal Concentration to 50 % of a test population.
LD₅₀: Lethal Dose to 50% of a test population (Median Lethal Dose).
EC₅₀: 50% of maximal Effective Concentration.
PBT: Persistent, Bioaccumulative and Toxic substance.
vPvB: Very Persistent and Very Bioaccumulative.

Classification abbreviations andacronyms
Repr. = Reproductive toxicity
Skin Sens. = Skin sensitisation
Aquatic Chronic = Hazardous to the aquatic environment (chronic)

Key literature references and sources for data
This SDS is prepared based on the information received from the product owner.
Source: European Chemicals Agency, http://echa.europa.eu/

Classification procedures according to Regulation (EC) 1272/2008
Skin Sens. 1 - H317: Repr. 2 - H361f: : Calculation method. Aquatic Chronic 3 - H412: : Calculation method.

Training advice
Read and follow manufacturer's recommendations. Only trained personnel should use this material.

Issued by 
Irmak TUNÇ/ CRAD gbf@crad.com.tr

Revision date 
15/09/2020

Revision 
0.0

Supersedes date 
15/09/2020

SDS number 
10681

Hazard statements in full 
H317 May cause an allergic skin reaction.
H361f Suspected of damaging fertility.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
H413 May cause long lasting harmful effects to aquatic life.

 
 

This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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