1.1 Product identifier 
Trade name: PowerResins Temp Resin / Description: Light-curing acrylic resin for DLP/SLA 3D printers for the fabrication of temporary crowns and bridges
1.2 Relevant identified uses of the substance or mixture and uses advised against 
Application of the substance/preparation Resin for DLP/SLA 3D printers / UV curable paint for figurines
1.3 Details of the supplier of the safety data sheet 
Manufacturer/Supplier : 3BFAB Technology Inc.
Illamurkuyu Mah. Canakkale Cad. Eren Plaza No:5 Kat:4 PK:34771 Ümraniye / Istanbul, Turkey 
+90 216 612 00 94
1.4 Emergency telephone number
+90 216 612 00 94

2.1 Classification of the substance or mixture 
Regulation (EC) No. 1272/2008
 

H315 - Skin Abrasion / Irritation, Hazard Category 2 
H317 - Sensitization - Skin, Hazard Category 1, 1A, 1B 
H319 - Serious Eye Damage / Eye Irritation, Hazard Category 2 
H335 - Specific Target Organ Toxicity, Single Exposure, Hazard Category 3 
H412 - Harmful to Aquatic Environment - Chronic Hazard, Category 3 
 

Full text of H statements: see Section 16
 

Hazard Statements: 
Causes skin irritation. 
May cause allergic skin reactions. 
Causes severe eye irritation. 
May cause respiratory irritation. 
Long-lasting, harmful effects on the aquatic environment.
 

2.2 Label elements 
Regulation (EC) No. 1272/2008 
Hazard components for labelling 
• isopropylidenediphenol peg-2 dimethacrylate 
• 2-hydroxyethyl methacrylate 
• diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide 
• Hydroxy propyl methacrylate 
• phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide

Hazard Marking : GHS07

Word of caution: Caution 
Hazard statements: 
H315 - Causes skin irritation.
H317 - May cause allergic skin reactions
H319 - Causes severe eye irritation.
H335 - May cause respiratory irritation.              
H412 - Long-lasting, harmful effect in the aquatic environment.
 

Precautionary Statements 
P261 - Avoid inhalation of dust/fume/gas/mist/vapor/spray.
P264 - Wash thoroughly with ... after handling.
P271 - Use only outdoors or in a well-ventilated area.
P272 - Contaminated clothing must not be allowed to leave the work area. 
P273 - Avoid release into the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
 

Intervention 
P312 - If you feel unwell, call the POISON CENTER or doctor/physician.
P302+P352 - IN CASE OF CONTACT WITH SKIN: Wash with plenty of soap and water.
P333+P313 If skin irritation or itching occurs: Get medical advice/attention.
P337+P313 - If eye irritation persists: Get medical advice/attention. 
P321 - Special treatment required (see label) 
P362+P364 - Remove contaminated clothing and wash before reuse.
P304+P340 - BY INHALATION: If breathing is difficult, remove the victim to fresh air and hold in a comfortable position to allow easy breathing.
P305+P351+P338 - EYE CONTACT: Rinse carefully with water for several minutes. Remove contact lenses if fitted and easy to do so. Continue rinsing.
 

Storage 
P405 - Store under lock and key.
P403+P233 - Store in a well-ventilated area. Keep the container tightly closed.

Disposal 
P501 - Dispose of waste/container at hazardous or special waste collection points.
 

2.3 Other hazards 
No information available.

3.2 Mixtures
Chemical characterization
Mixture of acrylic/ methacrylic resins with auxilliary matters. 

Hazardous components

Full text of H and EUH statements: see section 16.

4.1 Description of first aid measures 
General information 
Get medical attention immediately. Show this Safety Data Sheet to medical personnel.
After skin contact it 
is important to immediately remove the substance from the skin. If symptoms develop in case of any sensitization, make sure that further exposure is avoided. Remove contamination with soap and water or recognized skin cleanser. Seek medical attention if symptoms are severe or persist after washing.

After eye contact 
After eye contact, rinse with water for a sufficient time with eyelids open and consult an ophthalmologist immediately.

After ingestion 
Rinse mouth immediately and drink plenty of water. Get medical help immediately. Do not induce vomiting. In case of spontaneous vomiting, make sure that the vomit flows out unobstructed (risk of suffocation).

4.2 Significant acute and subsequent symptoms and effects 
No information available.

4.3 First indications for medical attention and special treatment 
Symptomatic treatment. May cause sensitization or allergic reactions in sensitive persons.

5.1 Extinguishing media

Suitable extinguishing m
Co-ordinate fire-fighting measures to the fire surroundings.

5.2 Special hazards arising from the substance or mixture
Non-flammable.

5.3 Recommendations for fire-fighting teams
Protective measures during fire fighting 
Avoid inhalation of fire gases or vapors. Evacuate the area. Keep upwind 
to avoid inhalation of gases, vapors and smoke. Ventilate before entering confined spaces. If a leak or spill has not ignited, use water spray to disperse vapors and protect men stopping the leak. Avoid discharging into the water environment. Control runoff water by containing it and keeping it away from sewers and waterways. If there is a risk of water pollution, notify the appropriate authorities.
Special protective equipment for firefighters 
Wear a positive pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. 
Firefighter clothing (helmets, protective boots and gloves) in accordance with European standard EN469 will provide a basic level of protection for chemical incidents.

6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions 

No action shall be taken without appropriate training or involving any personal risk. Keep unnecessary and unprotected personnel away from the spillage. Wear protective clothing as described in Section 8 of this safety data sheet. Follow the precautions described in this safety data sheet for safe handling. Wash thoroughly after handling a spillage. Ensure procedures and training are in place for emergency decontamination and disposal. Do not touch or walk on spilled material. Avoid contact with skin and eyes.

6.2 Environmental precautions 
Avoid spillage into drains, waterways or soil. Avoid discharge into the water environment. Large Spills: Notify the relevant authorities if environmental pollution occurs (sewage, waterways, soil or air).

6.3 Methods and materials for preservation and cleaning
Clean-up methods 
Wear protective clothing as described in Section 8 of this safety data sheet. Approach the spillage from downwind. 
Small Spills: If the product is water soluble, dilute the spillage with water and mop up.
Alternatively, or if insoluble in water, absorb the spillage with an inert, dry material and place in a suitable waste disposal container. 
Large Spills: If the leak cannot be stopped, evacuate the area. Discharge spilled material to a waste treatment facility or proceed as follows. Contain and absorb the spill with sand, soil or other non-combustible material. Place waste in labeled, leak-proof containers. Thoroughly clean contaminated objects and areas in accordance with environmental regulations. Contaminated absorbent may pose the same hazard as the spilled material. Wash the contaminated area with plenty of water. Wash thoroughly after handling a spillage. 
It's dangerous for the environment. Do not discharge into sewers. 
Dispose of waste at: Licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority.

6.4 Reference to other sections 
See Section 8 for personal protection. See Section 11 for additional information on health hazards. For additional information on ecological hazards see Section 12. For waste disposal see Section 13.

7.1 Precautions for safe use
Advice for safe handling 
Read and follow the manufacturer's recommendations. Wear protective clothing as described in Section 8 of this safety data sheet. Keep away from food, drink and animal feed. Handle all packages and containers carefully to minimize spills. Keep container tightly closed when not in use. 
Avoid discharge into the water environment. 
Do not handle until all safety precautions have been read and understood. 
Do not handle broken packages without protective equipment. 
Do not reuse empty containers.
Advice on general occupational hygiene 
Wash skin immediately if it becomes soiled. Remove contaminated clothing. Wash contaminated clothing before reuse. Do not eat, drink or smoke while using this product. Wash at the end of each shift and before eating, smoking and using the toilet. Change work clothes every day before leaving the workplace.

7.2 Safe storage conditions, including any incompatibilities
Requirements for storage rooms and vessels 
Store away from incompatible materials (see Section 10). Store in accordance with local legislation. Store only in the original container. Keep container tightly closed in a cool, well ventilated place. 
Keep containers upright. Protect containers from damage. Surround storage facilities with embankments to prevent soil and water pollution in case of spillage. The floor of the storage area should be impermeable, jointless and non-absorbent.

7.3 Specific end use(s) 
Light-curing material for the manufacture of dental splints and guides.
For use by trained specialized personnel.
 

8.1 Control parameters 

No identifying information.

8.2 Exposure controls

Protective equipment

Appropriate engineering controls 
Provide adequate ventilation. Personal, workplace environmental or biological monitoring may be required to determine the effectiveness of ventilation or other control measures and/or the need to use respiratory protective equipment. Use process enclosures, local exhaust ventilation or other engineering controls as the primary means to minimize worker exposure. Personal protective equipment should be used only if worker exposure cannot be adequately controlled by engineering control measures. Ensure that control measures are regularly inspected and maintained. Ensure that operators are trained to minimize exposure.

Eye/face protection 
If a risk assessment indicates that eye contact is possible, goggles conforming to an approved standard must be worn. Personal protective equipment for eye and face protection must comply with European Standard EN166. Unless the assessment indicates that a higher degree of protection is required, the following protection must be worn: Tight-fitting safety glasses.

Hand protection 
If a risk assessment indicates that skin contact is possible, chemical resistant, waterproof gloves conforming to an approved standard should be worn. The most suitable glove should be selected in consultation with the glove supplier/manufacturer who can provide information on the penetration time of the glove material. To protect hands from chemicals, gloves must comply with European Standard EN374. Check that gloves retain their protective properties during use, taking into account the data specified by the glove manufacturer, and replace gloves as soon as any deterioration is detected. frequent changes are recommended. For up to 4 hours of exposure, use gloves made of the following material: Butyl rubber. Nitrile rubber.

Other skin and body protection 
If a risk assessment indicates that skin contamination is possible, suitable footwear and additional protective clothing conforming to an approved standard should be worn.

Hygiene measures 
Provide eye wash station and safety shower. Contaminated work clothes should not be taken out of the workplace. Wash contaminated clothing before reuse. Clean equipment and work area daily. Good personal hygiene procedures must be practiced. Wash at the end of each shift and before eating, smoking and using the toilet. Do not eat, drink or smoke while using. Preventive industrial medical examinations must be carried out. Warn cleaning personnel of any hazardous properties of the product.

Respiratory protection 
If a risk assessment indicates that inhalation of contaminants is possible, respiratory protection conforming to an approved standard must be worn. Ensure that all respiratory protective equipment is suitable for its intended use and has the "CE" marking. Check that the respirator fits tightly and that the filter is changed regularly. Gas and combined filter cartridges must comply with European Standard EN14387. Full facepiece respirators with replaceable filter cartridges must comply with European Standard EN136. Half-mask and quarter-mask respirators with replaceable filter cartridges must comply with European Standard EN140.

Environmental exposure controls 
Keep container tightly closed when not in use. Emissions from ventilation or work process equipment should be controlled to ensure that they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to process equipment will be necessary to reduce emissions to acceptable levels. Store in a fenced area to prevent contamination of drains and/or waterways.

9.1 Information on basic physical and chemical properties 
Physical State: liquid 
Color: Tooth-like 
Odor: Slightly like esters
PH value: Not determined

Changes in physical condition
Melting point: Not determined
Initial boiling point and boiling range: Not determined
Flash point >100 °C DIN 51755
Lower explosion limits: Not determined
Upper explosion limits: Not determined
Decomposition temp: >=190 °C Not oxidizing.
Vapor pressure <1 hPa (at 20 °C)
Density (at 20 °C): 1.1 g/cm³ DIN 51757
Water solubility: Insoluble
Coefficient of separation: Not determined
Vapor density: Not determined
Evaporation rate: Not determined

9.2 Other information 
Solid content: Not determined

10.1 Reaction
No dangerous reactions when used in accordance with the provisions.
10.2 Chemical Stability
The product is stable under storage at normal ambient temperatures.
10.3 Possibility of Harmful Reaction
Reacts with: strong oxidizing agents, strong alkaline or acidic materials.
10.4 Situations to avoid
Ultraviolet light and sunlight initiate the polymerization of the product. Therefore, store only in tightly closed containers, away from any light source at 5°C - 25°C.
10.5 Incompatible materials
No information available.
10.6 Harmful decomposition products
Under normal conditions of storage and use, no hazardous decomposition products should be formed.

11.1 Information on toxicological effects

Acute toxicity
Based on available data, the classification criteria are not met.

Irritation and corrosivity
Causes skin irritation.
Causes serious eye irritation.

Sensitising effects
May cause an allergic skin reaction. (isopropylidenediphenol peg-2 dimethacrylate; 2-hydroxyethyl methacrylate; diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide; Hydroxy propyl methacrylate; phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide)

Carcinogenic/mutagenic/toxic effects for reproduction
Based on available data, the classification criteria are not met.

STOT-single exposure
May cause respiratory irritation. (isopropylidenediphenol peg-2 dimethacrylate)

STOT-repeated exposure
Based on available data, the classification criteria are not met.

Aspiration hazard
Based on available data, the classification criteria are not met.

Additional information on tests
This mixture is classified as hazardous according to regulation (EC) No. 1272/2008 [CLP].

12.1 Toxicity
Long-lasting, harmful effect in the aquatic environment.

12.2 Persistence and degradability
Persistence and degradability The product's degradability is not known.

12.3 Bioaccumulation potential
Bioaccumulation potential No relevant data on bioaccumulation.

12.4 Mobility in soil
No available data on mobility.

12.5 Results of PBT and vPVB assessment
Results of PBT and vPVB assessment. This product does not contain any substances classified as PBT or vPvB.

Coefficient of dispersion n-octanol/water

BCF

12.6 Other negative impacts
No supplementary information.

More information 
Do not allow to enter surface water or sewage. Do not allow to enter soil/subsoil.

13.1 Waste treatment methods

General information
Reuse or recycle products wherever possible. This material and its container must be disposed of safely. When handling waste, the safety precautions applicable to the handling of the product must be observed. Empty containers may retain product residues and therefore be potentially hazardous.

Disposal methods
Do not discharge into the sewer. Dispose of excess products and those that cannot be recycled through a licensed waste disposal contractor. Waste, residues, empty containers, discarded work clothes and contaminated cleaning materials should be collected in special containers and their contents labeled.

Land transport (ADR/RID)

14.1 UN number: No dangerous good in sense of this transport regulation.

14.2 UN proper shipping name: No dangerous good in sense of this transport regulation..

14.3 Transport hazard class(es): No dangerous good in sense of this transport regulation.

14.4 Packing group: No dangerous good in sense of this transport regulation..

Inland waterways transport (ADN)

14.1 UN number: No dangerous good in sense of this transport regulation.

14.2 UN proper shipping name: No dangerous good in sense of this transport regulation.

14.3 Transport hazard class(es): No dangerous good in sense of this transport regulation.

14.4 Packing group: No dangerous good in sense of this transport regulation.

Marine transport (IMDG)

14.1 UN number: No dangerous good in sense of this transport regulation.

14.2 UN proper shipping name: No dangerous good in sense of this transport regulation.

14.3 Transport hazard class(es): No dangerous good in sense of this transport regulation.

14.4 Packing group: No dangerous good in sense of this transport regulation.

Air transport (ICAO-TI/IATA-DGR)

14.1 UN number: No dangerous good in sense of this transport regulation.

14.2 UN proper shipping name: No dangerous good in sense of this transport regulation.

14.3 Transport hazard class(es): No dangerous good in sense of this transport regulation.

14.4 Packing group: No dangerous good in sense of this transport regulation.

14.6 Special precautions for user
No dangerous good in sense of this transport regulation.

14.7 Bulk transportation in accordance with Annex II of MARPOL Convention and IBC Code 
Not applicable.

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

National regulations
Health and Safety at Work etc Act 1974 (as amended). Carriage of Dangerous Goods and Use of Portable Pressure Equipment Regulations 2009 (SI 2009 No. 1348) (as amended) ["CDG 2009"]. EH40/2005 Workplace exposure limits.

EU legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of December 18, 2006 on the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH) (as amended). Commission Regulation (EU) 2015/830 of May 28, 2015. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labeling and packaging of substances and mixtures (as amended).

Seveso Directive - Control of major accident hazards
Not applicable.

15.2 Chemical Safety Assessment
No chemical safety assessment has been carried out.

Abbreviations and acronyms used in the safety data sheet
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.
ADN: European Agreement concerning the International Carriage of Dangerous Goods by Road
Waterways.
RID European Agreement concerning the International Carriage of Dangerous Goods by Rail.
IATA: International Air Transport Association.
ICAO: Technical Instructions for the Safe Transport of Dangerous Goods by Air.
IMDG: International Maritime Dangerous Goods.
CAS: Chemical Abstracts Service.
ATE: Acute Toxicity Estimate.
LC₅₀: Lethal Concentration up to 50% of a test population.
LD₅₀: Lethal Dose (Median Lethal Dose) up to 50% of a test population.
EC₅₀: 50% of the Maximum Effective Concentration.
PBT: Persistent, Bioaccumulative and Toxic substance.
vPvB: Very Persistent and Very Bioaccumulative.
Skin Sens. = Skin sensitivity
Aquatic Chronic = Harmful to the aquatic environment
Skin Irrit. = Skin Abrasion/Irritation
Eye Irrit. = Serious Eye Damage/Eye Irritation
STOT SE = Specific Target Organ Toxicity, Single exposure
Classification for mixtures and used evaluation method according to Regulation (EC) No. 1272/2008 [CLP]

Education advice
Read and follow the manufacturer's recommendations. Only trained personnel should handle this material.

Full hazard statements 
Full text of H and EUH statements:

Aquatic Chronic 3 Harmful to Aquatic Environment - Chronic hazard, Category 3 
STOT SE 3 Specific Target Organ Toxicity, Single exposure, Hazard Category 3
Eye Irrit. 2 Serious Eye Damage/Eye Irritation, Hazard Category 2 
Skin Irrit. 2 Skin Abrasion/irritation, Hazard Category 2 
Skin Sens. 1 Skin sensitization, Hazard Category 1
 

H315 - Causes skin irritation.
H317 - May cause allergic skin reaction.
H319 - Causes severe eye irritation.
H335 - May cause respiratory irritation.
H412 - Long lasting, harmful effect in aquatic environment.
 

Further Information
The information is based on our current level of knowledge. However, it does not guarantee product characteristics and does not create contractual legal rights. The purchaser of our product is solely responsible for compliance with applicable laws and regulations.