SG Resin Material Safety Data Sheet (MSDS)
This article provides information about the SG Resin Material Safety Data Sheet (MSDS) so that the reader can learn about the requirements for safe use of SG Resin.
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SG Resin Material Safety Data Sheet
SECTION I: Identification of the substance / mixture and of the company / undertaking
1.1 Product identifier
Product name PowerResins SG Resin
1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses
Light-curing resin for the production of removable base plates.
Non-recommended uses
Specific non-recommended uses have not been identified.
1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier: 3BFAB Technology Inc.
Illamurkuyu Mah. Canakkale Cad. Eren Plaza No:5 Kat:4 PK:34771 Ümraniye / Istanbul, Turkey
+90 216 612 00 94
1.4 Emergency telephone number:
+90 216 612 00 94
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification (EC 1272/2008)
H317 - Sensitization - Skin, Hazard Category 1, 1A, 1B
H361f - Reproductive System Toxicity, Hazard Category 2
H410 - Harmful to Aquatic Environment - Chronic Hazard, Category 1
H411 - Harmful to Aquatic Environment - Chronic Hazard, Category 2
H412 - Harmful to Aquatic Environment - Chronic Hazard, Category 3
Full text of H statements: see Section 16
May cause allergic skin reactions.
There is a suspicion of fertility damage.
Long-lasting, very toxic effect in the aquatic environment.
Long-lasting, toxic effects in the aquatic environment.
Long-lasting, harmful effects on the aquatic environment.
2.2. Label elements
Harmfulness Sign: GHS07, GHS09
Warning Word: Caution
Harmfulness Statements
H317 - May cause allergic skin reactions
H361f - Suspected harm to fertility.
H410 - Long-lasting, very toxic effect in aquatic environment.
H411 - Long-lasting, toxic effect in the aquatic environment.
H412 - Long-lasting, harmful effect in the aquatic environment
Precautionary Statements
P201 - Read special instructions before use.
P202 - Do not handle until all precautionary statements have been read and understood
P261 - Avoid breathing dust/fume/gas/mist/vapor/spray.
P272 - Contaminated clothing should not be allowed to leave the work area.
P273 - Avoid release into the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
Intervention
P302+P352 - IF IN CONTACT WITH SKIN: Wash with plenty of soap and water.
P333+P313 If skin irritation or itching occurs: Get medical advice/attention.
P321 - Special treatment required (see label)
P362+P364 - Remove contaminated clothing and wash before reuse.
P308+P313 In case of exposure or interaction IF: Get medical advice/attention.
P391 Collect spillage.
Storage
P405 - Store under lock and key.
Disposal
P501 - Dispose of waste/container at hazardous or special waste collection points.
2.3 Other Hazards
This product does not contain any substances classified as
PBT or vPvB.
SECTION 3: Composition / Information on Ingredient
3.2. Mixtures
Esterification products of 4,4'-isopropylidenediphenol, ethoxylated and 2-methylprop-2-enoic acid CAS number: 41637-38-1 |
40-60% |
Classification Aquatic Chronic 4 - H413 |
7,7,9(or 7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12- diazahexadecane-1,16-diyl bismethacrylate CAS number: 72869-86-4 |
10-20% |
Classification Skin Sens. 1B - H317 Aquatic Chronic 2 - H411 |
diphenyl(2,4,6- trimethylbenzoyl)phosphine oxide CAS number: 75980-60-8 EC number: 278-355-8 |
1-5% |
Classification Skin Sens. 1 - H317 Repr. 2 - H361f Aquatic Chronic 2 - H411 |
1,6-Hexa nediol dimethacrylate CAS number: 6606-59-3 EC number: 229-551-7 |
1 - < 5 % |
Classification Skin Irrit. 2, Eye Irrit. 2, STOT SE 3; H315 H319 H335 |
2-Hydrox yethyl methacrylate CAS number: 868-77-9 EC number: 212-782-2 |
1 - < 5 % |
Classification Skin Irrit. 2, Eye Irrit. 2, Skin Sens. 1; H315 H319 H317 |
The full text for all hazard statements is displayed in Section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures
General information
Get medical attention immediately. Show this Safety Data Sheet to the medical personnel.
Inhalation
Remove affected person from source of contamination. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Maintain an open airway. Loosen tight clothing such as a collar, tie, or belt. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Place the unconscious person on their side in the recovery position and ensure breathing can take place.
Skin contact
It is important to remove the substance from the skin immediately. In the event of any sensitization.
symptoms developing, ensure further exposure is avoided. Remove contamination with soap and water or a recognized skin cleansing agent. Get medical attention if symptoms are severe or persist after washing.
Eye contact
Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 10 minutes.
Protection of first aiders
First aid personnel should wear appropriate protective equipment during any rescue. Wash contaminated clothing thoroughly with water before removing it from the affected person, or wear gloves.
4.2. Most important symptoms and effects, both acute and delayed
General information
See Section 11 for additional information on health hazards. The severity of the symptoms described will vary depending on the concentration and the length of exposure.
Inhalation
Prolonged inhalation of high concentrations may damage the respiratory system.
Skin contact
May cause skin sensitization or allergic reactions in sensitive individuals. Prolonged contact may cause
dryness of the skin.
Eye contact
May cause temporary eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor
Treat symptomatically. May cause sensitization or allergic reactions in sensitive individuals.
SECTION 5: Fire-Fighting Measures
5.1 Fire Extinguishers
Suitable extinguishing agent
The product is not flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water mist. Use extinguishing media suitable for the surrounding fire.
Unsuitable extinguishing agent
Do not use water cannons as extinguishing agent, this will spread the fire.
5.2 Special hazards arising from the substance or mixture
Specific hazards
Containers may explode violently when heated due to excessive pressure build-up.
Hazardous combustion products
Thermal decomposition or combustion products may contain the following substances: Harmful gases or vapors.
5.3 Recommendations for fire-fighting teams
Protective measures during fire fighting
Avoid inhalation of fire gases or vapors. Evacuate the area. Keep upwind
to avoid inhalation of gases, vapors and smoke. Ventilate before entering confined spaces. If a leak or spill has not ignited, use water spray to disperse vapors and protect men stopping the leak. Avoid discharging into the water environment. Control runoff water by containing it and keeping it away from sewers and waterways. If there is a risk of water pollution, notify the appropriate authorities.
Special protective equipment for firefighters
Wear a positive pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing.
Firefighter clothing (helmets, protective boots and gloves) in accordance with European standard EN469 will provide a basic level of protection for chemical incidents.
SECTION 6: Accidental Spill Precautionsthe
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions
No action shall be taken without appropriate training or involving any personal risk. Keep unnecessary and unprotected personnel away from the spillage. Wear protective clothing as described in Section 8 of this safety data sheet. Follow precautions for safe handling described in this safety data sheet. Wash thoroughly after dealing with a spillage. Ensure procedures and training for emergency decontamination and disposal are in place. Do not touch or walk into spilled material. Avoid contact with skin and eyes.
6.2. Environmental precautions
Environmental precautions
Avoid discharge into drains or watercourses or onto the ground. Avoid discharge to the aquatic environment. Large Spillages: Inform the relevant authorities if environmental pollution occurs (sewers, waterways, soil or air).
6.3. Methods and material for containment and cleaning up
Methods for cleaning up
Wear protective clothing as described in Section 8 of this safety data sheet. Approach the spillage from upwind. Small Spillages: If the product is soluble in water, dilute the spillage with water and mop it up.
Alternatively, or if it is not water-soluble, absorb the spillage with an inert, dry material and place it in a suitable waste disposal container. Large Spillages: If leakage cannot be stopped, evacuate area. Flush spilled material into an effluent treatment plant, or proceed as follows. Contain and absorb spillage with sand, earth or other non- combustible material. Place waste in labelled, sealed containers. Clean contaminated objects and areas thoroughly, observing environmental regulations. The contaminated absorbent may pose the same hazard as the spilled material. Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage. Dangerous for the environment. Do not empty into drains. Dispose of waste to
licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority.
6.4. Reference to other sections
Reference to other sections
For personal protection, see Section 8. See Section 11 for additional information on health hazards. See
Section 12 for additional information on ecological hazards. For waste disposal, see Section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe use
Precautions for use
Read and follow the manufacturer's recommendations. Wear protective clothing as described in Section 8 of this safety data sheet. Keep away from food, drink, and animal feed. Handle all packages and containers carefully to minimize spills. Keep the container tightly closed when not in use.
There is a suspicion of fertility damage.
Avoid discharge into the water environment.
Do not handle until all safety precautions have been read and understood.
Do not handle broken packages without protective equipment.
Do not reuse empty containers.
Advice on general occupational hygiene
Wash skin immediately if it becomes soiled. Remove contaminated clothing. Wash contaminated clothing before reuse. Do not eat, drink or smoke while using this product. Wash at the end of each shift and before eating, smoking and using the toilet. Change work clothes every day before leaving the workplace.
7.2 Safe storage conditions, including any incompatibilities
Storage precautions
Store away from incompatible materials (see Section 10). Store in accordance with local legislation. Store only in the original container. Store in a tightly closed, cool and well-ventilated place.
Keep containers upright. Protect containers from damage. Surround storage facilities with embankments to prevent soil and water pollution in case of spillage. The floor of the storage area should be impermeable, jointless, and non-absorbent.
7.3 Specific end use(s)
For use by trained specialized personnel.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
No identifying information.
8.2. Exposure controls
Protective equipment
Appropriate engineering controls
Provide adequate ventilation. Personal, workplace environment or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Use process enclosures, local exhaust ventilation or other engineering controls as the primary means to minimise worker exposure. Personal protective equipment should only be used if worker exposure cannot be controlled adequately by the engineering control measures. Ensure control measures are regularly inspected and maintained. Ensure operatives are trained to minimise exposure.
Eye/face protection
Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. Personal protective equipment for eye and face protection should comply with European Standard EN166. Unless the assessment indicates a higher degree of protection is required, the following protection should be worn: Tight-fitting safety glasses.
Hand protection
Chemical-resistant, impervious gloves complying with an approved standard should be worn if a risk assessment indicates skin contact is possible. The most suitable glove should be chosen in consultation with the glove supplier/manufacturer, who can provide information about the breakthrough time of the glove material. To protect hands from chemicals, gloves should comply with European Standard EN374. Considering the data specified by the glove manufacturer, check during use that the gloves are retaining their protective properties and change them as soon as any deterioration is detected. Frequent changes
are recommended. For exposure up to 4 hours, wear gloves made of the following material: Butyl rubber. Nitrile rubber.
Other skin and body protection
Appropriate footwear and additional protective clothing complying with an approved standard should be worn if a risk assessment indicates skin contamination is possible.
Hygiene measures
Provide eyewash station and safety shower. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Clean equipment and the work area every day. Good personal hygiene procedures should be implemented. Wash at the end of each work shift and before eating, smoking and using the toilet. When using do not eat, drink or smoke. Preventive industrial medical examinations should be carried out. Warn cleaning personnel of any hazardous properties of the product.
Respiratory protection
Respiratory protection complying with an approved standard should be worn if a risk assessment indicates inhalation of contaminants is possible. Ensure all respiratory protective equipment is suitable for its intended use and is ‘CE’-marked. Check that the respirator fits tightly and the filter is changed regularly. Gas and combination filter cartridges should comply with European Standard EN14387. Full face mask respirators with replaceable filter cartridges should comply with European Standard EN136. Half mask and quarter mask respirators with replaceable filter cartridges should comply with European Standard EN140.
Environmental exposure controls
Keep container tightly sealed when not in use. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Store in a demarcated bunded area to prevent release to drains and/or watercourses.
SECTION 9: Physical and chemical properties
9.1 Knowledge of basic physical and chemical properties
Appearance: Liquid
Color: Transparent
Odor: Odorless
Odor threshold: No information available.
pH. No information available.
Melting point: No information available.
Initial boiling point and range: No information available.
Flash point: No information available.
Evaporation rate: No information available.
Flammability (solid, gas): No information available.
Upper/lower flammability or explosion limits: No information available.
Vapor pressure: No information available.
Vapor density: No information available.
Resolution(s): No information available.
Spontaneous ignition temperature: The product does not ignite spontaneously.
Decomposition Temperature: 300°C
Viscosity, kinematic: 1900-2200 mPa.s at 25oC
Explosive properties: No information available.
Oxidizing properties: No information available.
9.2 Other information
No supplementary information.
SECTION 10: Stability and reactivity
10.1 Reaction
It is stable under normal conditions.
10.2 Chemical stability
Stable at normal ambient temperatures and when used as recommended. Stable under prescribed storage conditions.
10.3 Possibility of harmful reaction
No known hazardous reactions under normal conditions of use.
10.4 Situations to avoid
Ultraviolet light and sunlight initiate the polymerization of the product. Therefore, store only in tightly closed containers, away from any light source at 5°C - 25°C.
10.5 Incompatible materials
It is unlikely that a particular material or group of materials will react with the product in such a way as to create a hazardous situation.
10.6 Harmful decomposition products
Under normal conditions of storage and use, no hazardous decomposition products should be formed.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity - oral
Notes (oral LD₅₀) Based on available data the classification criteria are not met.
Acute toxicity - dermal
Notes (dermal LD₅₀). Based on available data the classification criteria are not met.
Acute toxicity - inhalation.
Notes (inhalation LC₅₀) Based on available data the classification criteria are not met.
Serious eye damage/irritation
Serious eye damage/irritation Based on available data the classification criteria are not met.
Respiratory sensitization
Respiratory sensitisation Based on available data the classification criteria are not met.
Skin sensitization
Skin sensitization May cause skin sensitization or allergic reactions in sensitive individuals.
Germ cell mutagenicity
Genotoxicity - in vitro Based on available data the classification criteria are not met.
Carcinogenicity
Carcinogenicity Based on available data the classification criteria are not met.
IARC carcinogenicity None of the ingredients are listed or exempt.
Reproductive toxicity
Reproductive toxicity - fertility Suspected of damaging fertility.
Reproductive toxicity -
development Based on available data the classification criteria are not met.
Specific target organ toxicity - single exposure
STOT - single exposure Not classified as a specific target organ toxicant after a single exposure.
Specific target organ toxicity - repeated exposure
STOT - repeated exposure Not classified as a specific target organ toxicant after a single exposure.
Aspiration hazard
Aspiration hazard Based on available data the classification criteria are not met.
General information May damage fertility. The severity of the symptoms described will vary depending on the concentration and the length of exposure.
Inhalation Prolonged inhalation of high concentrations may damage the respiratory system.
Ingestion May cause sensitization or allergic reactions in sensitive individuals. Gastrointestinal symptoms, including upset stomach. Fumes from the stomach contents may be inhaled, resulting in the same symptoms as inhalation.
Skin contact May cause skin sensitization or allergic reactions in sensitive individuals. Prolonged contact may cause dryness of the skin.
Eye contact May cause temporary eye irritation.
Route of exposure Ingestion Inhalation Skin and/or eye contact
Target organs No specific target organs known.
Medical considerations Skin disorders and allergies.
SECTION 12: Ecological information
12.1 Toxicity
Toxicity Aquatic Chronic 3 - H412 Harmful to aquatic life with long-lasting effects.
12.2 Persistence and Degradability
Persistence and degradability The degradability of the product is not known.
12.3 Bioaccumulative potential
Bioaccumulative potential No data is available on bioaccumulation.
12.4 Mobility in soil
Mobility The product contains volatile substances that may spread in the atmosphere.
12.5 Results of PBT and vPvB assessment
Results of PBT and vPvB assessment. This product does not contain any substances classified as PBT or vPvB.
12.6 Other adverse effects
Other adverse effects None known.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
General information
Reuse or recycle products wherever possible. This material and its container must be disposed of in a safe way. When handling waste, the safety precautions applied to handling the product should be considered. Care should be taken when handling emptied containers that have not been thoroughly cleaned or rinsed out. Empty containers or liners may retain some product residues and hence be potentially hazardous.
Disposal methods
Do not empty into drains. Dispose of surplus products and those that cannot be recycled via a licensed waste disposal contractor. Waste, residues, empty containers, discarded work clothes, and contaminated cleaning materials should be collected in designated containers, and labeled with their contents.
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN instructions
Land transportation (ADR/RID)
14.1 UN number: No hazardous substance within the meaning of this transport regulation.
14.2 Proper UN transport name: No dangerous goods within the meaning of this transport regulation.
14.3 Transport hazard class(es): No hazardous substance in terms of this transport regulation.
14.4 Packaging group: No hazardous substance in the sense of this transport regulation.
Maritime transportation (IMDG)
14.1 UN number: No dangerous goods within the meaning of this transport regulation.
14.2 Proper UN Transport name: No dangerous goods within the meaning of this transport regulation.
14.3 Transport hazard class(es): No hazardous substance in terms of this transport regulation.
14.4 Packaging group: No hazardous substance in the sense of this transport regulation.
Air transportation (ICAO-TI/IATA-DGR)
14.1 UN number: No dangerous goods within the meaning of this transport regulation.
14.2 Proper UN transport name: No dangerous goods within the meaning of this transport regulation.
14.3 Transport hazard class(es): No hazardous substance in terms of this transport regulation.
14.4 Packaging group: No hazardous substance in the sense of this transport regulation.
14.6 Special precautions for the user
No hazardous substances are within the meaning of these transport regulations.
14.7 Bulk transportation in accordance with Annex II of the MARPOL Convention and IBC Code
Not applicable.
SECTION 15: Regulatory Information
15.1 Safety, health, and environmental regulations/legislation specific for the substance or mixture
National regulations
Health and Safety at Work etc. Act 1974 (as amended). The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009 (SI 2009 No. 1348) (as amended) ["CDG 2009"]. EH40/2005 Workplace exposure limits.
EU legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (as amended). Commission Regulation (EU) No 2015/830 of 28 May 2015. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended).
Seveso Directive - Control of major accident hazards
Not applicable.
15.2 Chemical safety assessment
No chemical safety assessment has been carried out.
SECTION 16: Other information
Abbreviations and acronyms used in the safety data sheet
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.
ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways.
RID: European Agreement concerning the International Carriage of Dangerous Goods by Rail.
IATA: International Air Transport Association.
ICAO: Technical Instructions for the Safe Transport of Dangerous Goods by Air.
IMDG: International Maritime Dangerous Goods.
CAS: Chemical Abstracts Service.
ATE: Acute Toxicity Estimate.
LC₅₀: Lethal Concentration to 50 % of a test population.
LD₅₀: Lethal Dose to 50% of a test population (Median Lethal Dose).
EC₅₀: 50% of maximal Effective Concentration.
PBT: Persistent, Bioaccumulative and Toxic substance.
vPvB: Very Persistent and Very Bioaccumulative.
Classification abbreviations andacronyms
Repr. = Reproductive toxicity
Skin Sens. = Skin sensitisation
Aquatic Chronic = Hazardous to the aquatic environment (chronic)
Key literature references and sources for data
This SDS is prepared based on the information received from the product owner.
Source: European Chemicals Agency, http://echa.europa.eu/
Training advice
Read and follow the manufacturer's recommendations. Only trained personnel should use this material.
Full hazard statements
Full text of H and EUH statements:
Aquatic Chronic 1 Harmful to the Aquatic Environment - Chronic hazard, Category 1
Aquatic Chronic 2 Harmful to the Aquatic Environment - Chronic hazard, Category 2
Aquatic Chronic 3 Harmful to the Aquatic Environment - Chronic hazard, Category 3
Repr. 2 Reproductive System Toxicity, Hazard Category 2
Skin Sens. 1 Skin sensitization, Hazard Category 1
H317 - Causes allergic skin reactions
H361f - Suspected harm to fertility.
H410 - Long-lasting, very toxic effect in the aquatic environment
H411 - Long-lasting, toxic effect in the aquatic environment
H412 - Long-lasting, harmful effect in the aquatic environment
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.